Diverse Coordination Numbers and Geometries in Pyridyl Adducts of Lanthanide(III) Complexes Based on β-Diketonate

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چکیده

Ten mononuclear rare earth complexes of formula [La(btfa)3(H2O)2] (1), [La(btfa)3(4,4′-Mt2bipy)] (2), [La(btfa)3(4,4′-Me2bipy)2] (3), [La(btfa)3(5,5′-Me2bipy)2] (4), [La(btfa)3(terpy)] (5), [La(btfa)3(phen)(EtOH)] (6), [La(btfa)3(4,4′-Me2bipy)(EtOH)] (7), [La(btfa)3(2-benzpy)(MeOH)] (8), [Tb(btfa)3(4,4′-Me2bipy)] (9) and (Hpy)[Eu(btfa)4] (10), where btfa = 4,4,4-trifuoro-1-phenylbutane-1,3-dionato anion, 4,4′-Mt2bipy 4,4′-dimethoxy-2,2′-bipyridine, 4,4′-Me2bipy 4,4′-dimethyl-2,2′-bipyridine, 5,5′-Me2bipy 5,5′-dimethyl-2,2′-bipyridine, terpy 2,2′:6′,2′-terpyridine, phen 1,10-phenathroline, 2-benzpy 2-(2-pyridyl)benzimidazole, Hpy pyridiniumH+ cation) have been synthesized structurally characterized. The display coordination numbers (CN) eight for 1, 2, 9, 10, nine 5, 6, 7, 8 ten 3 4. solid-state luminescence spectra Tb-9 Eu-10 showed the same characteristic bands predicted from Tb(III) Eu(III) ions. Overall Quantum Yield measured (ϕTOT) at excitation wavelength 371 nm both compounds yielded 1.04% 9 up to 34.56% 10.

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ژورنال

عنوان ژورنال: Inorganics (Basel)

سال: 2021

ISSN: ['2304-6740']

DOI: https://doi.org/10.3390/inorganics9100074